Oil and the environment - Index CATOR - Oil and the environment    
Why do we have to change lubricants ?
Basically, there are two important reasons for changing a lubricating oil:
  
1st -
contamination internal 
external
2nd - consumption of additives of the lubricant, causing it to lose its properties 

 
   
 
Contamination

This is the principal cause for changing a lubricant

External contaminants:

Dirt, paper, rags, threads, iron filings, dust, earth, damp, steam, water etc.

Other liquids which may enter the system, corrosive or non-corrosive, such as refrigerating fluids, cleaning products, acids, solvents, paint, mixtures of other oils, metallic particles from machinery, mechanization, decomposition of sealant, inadequate joins.

Internal contaminants:

Internal wear and tear caused because the lubricant has lost its properties and no longer works.

Rust, produced because oxygen enters the system through air or water and starts a process of corrosion.

Formation of sludge - all systems are exposed, if only from time to time, to temperatures and pressures higher than normal, and this causes the oil to suffer an important thermal shock - it cracks, forms charcoal and oxidizes, causing acid formation. The metallic particles act as catalysts for collateral and parallel reactions, and the effects are multiplied.

Formation of scum, if air or detergents have entered the pumps.

Cavities may be formed, and produce problems in lubrication or refrigeration.

Sometimes the maintenance teams in companies, with the best intentions, introduce additives that can cause serious problems if the state of the lubricant is unknown.

All lubricants should be perfectly prepared for the function they have to carry out - they shouldn't be reinforced.

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Consumption of additives

Many additives are consumed and/or change their chemical structure due to external effects, and no longer carry function correctly. At this point we either top up, or change the oil for new, and thus we have generated a used oil that must be treated as a very special waste.

Corrosion inhibitors:

Corrosion inhibitors act firstly as neutralizers for acids produced by oxidizing, and secondly form a protective coating over metallic surfaces.

When the action of the inhibitors is reduced, oxygen attack is produced, and consequently the sludge forms. This changes the characteristics of the oil, the degree of acidity progresses, the oil blackens, and performance is reduced.

Corrosion inhibitors are attracted to metallic surfaces, even to particles in suspension and to dirt, and consequently are in part eliminated during filtering. They are also attracted to contaminating fluids and are removed with them during purification.

They can also oxidize, becoming soluble in water and lose efficiency.

Viscosity:

The changes in viscosity that are produced during use are also a clear indication of the capacity of a lubricant. If there is an increase this means that there is advanced oxidization and/or contamination from dirt or water, and if there is a decrease, it means that there is contamination from a solvent, another oil with lower viscosity, or shearing of the oil in use. All these points endanger the system.

Anti- wear and tear additives and E.P.:

These additives prevent contact between metallic surfaces in the points where the contact pressure increases considerably, or if the temperature rises greatly, as this decreases the viscosity of the oil, and may cause a rupture in the lubricating coating, causing the two surfaces to touch and thus increased and premature wear and tear. Also, due to time, presence of contaminants, or severe work conditions, these additives degrade, hydrolyse, oxidize and no longer work.

Dispersing additives:

The appearance of dirt, water etc. begins at the moment the lubricant begins to work. The dispersing additives make the dirt and other products of oxidization remain in suspension and dispersed throughout the oil, thus avoiding their deposit in key points of the system where they would cause problems.

Logically, these additives can also degrade or even be inefficient if there is a high level of oxidation and contamination.

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